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773808 Sigma-Aldrich

Cyanomethyl [3-(trimethoxysilyl)propyl] trithiocarbonate

95% (GC)

Synonym: Carbonotrithioic acid, Cyanomethyl 3-(trimethoxysilyl)propyl ester, clickable RAFT agent, silane RAFT agent, surface-initiated RAFT agent

  • CAS Number 1050502-37-8

  • Empirical Formula (Hill Notation) C9H17NO3S3Si

  • Molecular Weight 311.52

  •  MDL number MFCD24386382

  •  PubChem Substance ID 329767639

  •  NACRES NA.23

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Properties

Related Categories Materials Science, Polymer Science, RAFT Agents, Reagents for Controlled Radical Polymerization, Reagents for Polymerization,
Quality Level   100
assay   95% (GC)
refractive index   n20/D 1.553
density   1.219 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   CO[Si](CCCSC(=S)SCC#N)(OC)OC
InChI   1S/C9H17NO3S3Si/c1-11-17(12-2,13-3)8-4-6-15-9(14)16-7-5-10/h4,6-8H2,1-3H3
InChI key   NGRLZFIXIPQVRW-UHFFFAOYSA-N

Description

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

Silane functionalized RAFT agent for surface functionalization; RAFT reagent with a trimethoxysilyl group that can be attached to surfaces. Especially suited for the polymerization of styrene; acrylate and acrylamide monomers. Controlled radical polymerization; Chain Transfer Agent (CTA)

Packaging

1 g in glass bottle

Legal Information

Sold for Research Purposes only: See sigma-aldrich.com/raftlicense Patents: WO98/01478; WO99/311444

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Protein and Peptide Polymer Conjugates

1Department of Chemistry, The University of Warwick, Coventry CV4 7AL, U.K. 2Warwick Medical School, The University of Warwick, Coventry CV4 7AL, U.K. 3Faculty of Pharmacy and Pharmaceutical Sciences...
Matthias Hartlieb,1 Raoul Peltier,1 Sébastien Perrier1,2,3*
Material Matters, 2017, 12.2
Keywords: Aminolysis, Bacterial conjugations, Biological processes, Biomaterials, Click chemistry, Cycloadditions, Degradations, Gene expression, Growth factors, Immobilization, Michael Addition, Nanotubes, PEGylations, Peptide synthesis, Pharmaceutical, Polymerization reactions, Post translational modifications, Purification, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations, Solid phase peptide synthesis, Solvents

Peer-Reviewed Papers
15

References

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