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804010 Sigma-Aldrich

Co(salen,t-Bu, t-Bu)Cl

  • Empirical Formula (Hill Notation) C36H52ClCoN2O2

  • Molecular Weight 639.20

  •  PubChem Substance ID 329768839

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt Catalysts More...
form   powder
reaction suitability   reagent type: catalyst
core: cobalt
mp   250 °C
storage temp.   2-8°C
SMILES string   Cl[Co]1OC(C(C(C)(C)C)=CC(C(C)(C)C)=C2)=C2/C=N/[C@](CCCC3)([H])[C@@]3([H])/N=C/C(C=C(C(C)(C)C)C=C4C(C)(C)C)=C4O1
InChI   1S/C36H54N2O2.ClH.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1
InChI key   DIPYCKRNYQWVPM-RUIQGICGSA-K

Description

Application

When utilized with organosilanes, catalytic amounts of Co(salen,t-Bu, t-Bu)Cl effects the isomerization of terminal alkenes.

Packaging

500 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Simplified Olefin Isomerization by Cobalt/Silane

Recently, the Shenvi lab has repurposed Jacobsen’s cobalt chloride complex, Co(salen,t-Bu, t-Bu)Cl, to enable positional isomerization of terminal alkenes using reversible hydrogen atom transfer (HAT...
Keywords: Catalysis, Cycloisomerizations, Isomerizations, Reductions

Peer-Reviewed Papers
15

References

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