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A24001 Sigma-Aldrich

Acrolein diethyl acetal

96%

Synonym: 3,3-Diethoxy-1-propene

  • CAS Number 3054-95-3

  • Linear Formula CH2=CHCH(OCH2CH3)2

  • Molecular Weight 130.18

  •  Beilstein/REAXYS Number 1701567

  •  EC Number 221-276-0

  •  MDL number MFCD00009239

  •  PubChem Substance ID 24890652

  •  NACRES NA.22

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Properties

Related Categories Acetals, Ketals & Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds More...
InChI Key   MCIPQLOKVXSHTD-UHFFFAOYSA-N
assay   96%
refractive index   n20/D 1.398 (lit.)
bp   125 °C (lit.)
density   0.854 g/mL at 25 °C (lit.)

Description

Application

Acrolein diethyl acetal is widely used to carry out chemoselective Heck arylation to synthesize either 3-arylpropanoate esters or cinnamaldehyde derivatives.

It can also be used as one of the precursors to synthesize natural products like (−)-(Z)-Deoxypukalide, (−)-Laulimalide, botryodiplodin, neolaulimalide and isolaulimalide.

Packaging

25, 100 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2374 3 / PGII
WGK Germany 
3
RTECS 
AS1370000
Flash Point(F) 
59 °F
Flash Point(C) 
15 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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