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A88255 Sigma-Aldrich

p-Anisidine

99%

Synonym: 4-Aminoanisole, 4-Methoxyaniline

  • CAS Number 104-94-9

  • Linear Formula CH3OC6H4NH2

  • Molecular Weight 123.15

  •  Beilstein/REAXYS Number 471556

  •  MDL number MFCD00007864

  •  PubChem Substance ID 24891372

  •  NACRES NA.22

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Properties

Related Categories Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds - Organic Building Blocks,
InChI Key   BHAAPTBBJKJZER-UHFFFAOYSA-N
assay   99%
autoignition temp.   959 °F
bp   240-243 °C (lit.)
mp   56-59 °C (lit.)

Description

Application

p-Anisidine can undergo aerobic oxidation in the presence of gold catalysts to form aromatic azo compounds.
p-Anisidine can be used:
•  In the diastereoselective and enantioselective synthesis of CF3-substituted azoridines catalyzed by a chiral Bronsted acid.
•  To prepare 4-organoselenium-quinolines through multi-component Povarov reaction with ethyl glyoxylate and ethynyl(phenyl)selane, catalyzed by Yb(OTf)3.
•  As a starting material to synthesize 3-fluoro-6-methoxyquinoline in two steps.,
•  To prepare N-PMP protected α-aminopropargylphosphonates by reacting with terminal alkynes and diethyl formylphosphonate hydrate using silver(I) triflate as a catalyst.

Packaging

1 kg in glass bottle

5, 100, 250 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN2811 - class 6.1 - PG 3 - EHS - RQ - Toxic solids, organic, n.o.s. HI: all
WGK Germany 
3
Flash Point(F) 
251.6 °F
Flash Point(C) 
122 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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