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B91005 Aldrich

tert-Butyl carbazate

98%

Synonym: tert-Butoxycarbonyl hydrazide, Boc-hydrazide

  • CAS Number 870-46-2

  • Linear Formula (CH3)3COCONHNH2

  • Molecular Weight 132.16

  •  Beilstein Registry Number 1756967

  •  EC Number 212-795-3

  •  MDL number MFCD00007593

  •  PubChem Substance ID 24892122

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Properties

Related Categories Amine Protection, Chemical Biology, Chemical Synthesis, Other Protecting and Derivatizing Reagents, Peptide Chemistry,
InChI Key   DKACXUFSLUYRFU-UHFFFAOYSA-N
assay   98%
bp   63-65 °C/0.1 mmHg(lit.)
mp   39-42 °C(lit.)

Description

Packaging

5, 25, 100, 500 g in poly bottle

Application

Employed in a palladium-catalyzed cross-coupling with vinyl halides leading to N-Boc-N-alkenylhydrazines.
Reagent used in solid phase peptide synthesis and in α-amino aldehyde optical purity determinations. Condenses with aldehydes to form hydrazones which are intermediates in the synthesis of HIV-1 protease inhibitors.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
197.6 °F
Flash Point(C) 
92 °C

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Protocols & Articles
Peer-Reviewed Papers
15

References

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901606 tert-Butyl carbazate solution, 1.0 M in dichloromethane

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