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29920 Sigma-Aldrich

Diethyl cyclopropane-1,1-dicarboxylate

purum, ≥97.0% (GC)

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Properties

Related Categories Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters,
grade   purum
assay   ≥97.0% (GC)
contains   ~0.05% hydroquinone monomethyl ether as stabilizer
refractive index   n20/D 1.433 (lit.)
  n20/D 1.433
bp   94-96 °C/10 mmHg (lit.)
density   1.055 g/mL at 25 °C (lit.)
SMILES string   CCOC(=O)C1(CC1)C(=O)OCC
InChI   1S/C9H14O4/c1-3-12-7(10)9(5-6-9)8(11)13-4-2/h3-6H2,1-2H3
InChI key   KYYUCZOHNYSLFV-UHFFFAOYSA-N

Description

General description

Diethyl cyclopropane-1,1-dicarboxylate undergoes ring-opening addition reactions with various nucleophilic reagents.

Other Notes

Review of electrophilic cyclopropanes

Safety & Documentation

Safety Information

WGK Germany 
WGK 3
Flash Point(F) 
188.6 °F - closed cup
Flash Point(C) 
87 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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