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  • 07026 - [4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl)phenyl] diphenylphosphine

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07026 Sigma-Aldrich

[4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl)phenyl] diphenylphosphine

≥99%

Synonym: Diphenyl[4-(1H,1H,2H,2H-perfluorodecyl)phenyl]phosphine

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Fluorous Synthesis, Phosphine Compounds, Phosphine Ligands,
assay   ≥99%
mp   81-85 °C
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
reaction type: Fluorous synthesis
SMILES string   FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI   1S/C28H18F17P/c29-21(30,22(31,32)23(33,34)24(35,36)25(37,38)26(39,40)27(41,42)28(43,44)45)16-15-17-11-13-20(14-12-17)46(18-7-3-1-4-8-18)19-9-5-2-6-10-19/h1-14H,15-16H2
InChI key   UPXCRVHPPXSSDG-UHFFFAOYSA-N

Description

Legal Information

Product of Fluorous Technologies, Inc. Use of this compound may be protected by U.S. patents 6,156,896; 5,859,247; 5,777,121 and 6,673,539.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

F-DIAD

In a typical Mitsunobu reaction between an acidic pronucleophile and an alcohol promoted by diisopropylazodicarboxylate (DIAD) and triphenylphosphine, the desired product is contaminated by reagent d...
ChemFiles Volume 4 Article 9
Keywords: Mitsunobu Reaction, Solid phase extractions

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