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114081 Sigma-Aldrich

4-(Benzyloxy)benzyl chloride

97%

Synonym: 4-Chloromethyl-α-phenylanisole

  • CAS Number 836-42-0

  • Linear Formula C6H5CH2OC6H4CH2Cl

  • Molecular Weight 232.71

  •  Beilstein/REAXYS Number 882526

  •  EC Number 212-648-3

  •  MDL number MFCD00000916

  •  PubChem Substance ID 24847156

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C14, Chemical Synthesis, Ethers, Organic Building Blocks,
Quality Level   200
assay   97%
mp   77-79 °C (lit.)
storage temp.   2-8°C
SMILES string   ClCc1ccc(OCc2ccccc2)cc1
InChI   1S/C14H13ClO/c15-10-12-6-8-14(9-7-12)16-11-13-4-2-1-3-5-13/h1-9H,10-11H2
InChI key   UYQPSKUPEXAQRJ-UHFFFAOYSA-N

Description

General description

4-(Benzyloxy)benzyl chloride acts as a solid support to readily determine the loading of the corresponding polymer-bound acids by direct cleavage. This was determined while studying the coupling of substituted aromatic, heterocyclic, and alkyl carboxylates to the resin.

Application

4-(benzyloxy)benzyl chloride is used in the preparation of 4-aryl-3,4-dihydropyrimidine-5-carboxylates (DHPMs) which exhibits a wide spectrum of biological effects.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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