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116327 Sigma-Aldrich

2-Chloro-4-methylpyridine

98%

Synonym: 2-Chloro-4-picoline

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Properties

Related Categories Building Blocks, C6, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks,
assay   98%
refractive index   n20/D 1.529 (lit.)
bp   194-195 °C (lit.)
density   1.142 g/mL at 25 °C (lit.)
SMILES string   Cc1ccnc(Cl)c1
InChI   1S/C6H6ClN/c1-5-2-3-8-6(7)4-5/h2-4H,1H3
InChI key   MZVSTDHRRYQFGI-UHFFFAOYSA-N

Description

General description

2-Chloro-4-methylpyridine (2-Chloro-4-picoline) reacts with 3,5-bis(trifluoromethyl)phenylboronic acid to form 2-(3,5-bis(trifluoromethyl)phenyl)-4-methylpyridine by palladium-catalyzed cross-coupling reaction.

2-Chloro-4-picoline (2-Chloro-4-methylpyridine) has been used in the determination of gas-phase basicity of several relatively small organic molecules that are used in the MALDI.

Packaging

5, 25 mL in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

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References

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