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122440 Aldrich

Thianthrene

97%

  • CAS Number 92-85-3

  • Empirical Formula (Hill Notation) C12H8S2

  • Molecular Weight 216.32

  •  Beilstein Registry Number 83046

  •  EC Number 202-197-0

  •  MDL number MFCD00005065

  •  PubChem Substance ID 24847488

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Properties

Related Categories Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Other Heterocyclic Building Blocks, S-Containing More...
InChI Key   GVIJJXMXTUZIOD-UHFFFAOYSA-N
assay   97%
bp   364-366 °C(lit.)
mp   151-155 °C(lit.)
solubility   DMF: soluble
  H2O: insoluble

Description

Packaging

25 g in glass bottle

Application

Thianthrene has been used to study aqueous solubilities of several solid nitrogen-, sulfur- and oxygen-containing heterocyclic derivatives of anthracene, phenanthrene and fluorene. It has been used in determination of partition coefficients of several sulfur-containing aromatics in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and supercritical carbon dioxide.

General description

Thianthrene undergoes liquid phase tert-butylation in the presence of large pore zeolites and mesoporous aluminosilicates catalyst to yield tert-butyl derivatives. Thianthrene on oxidation in the presence of hydrogen peroxide and ligninase as catalyst from Phanerochaete chrysosporium yields thianthrene monosulfoxide.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

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Protocols & Articles
Peer-Reviewed Papers
15

References

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