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122831 Sigma-Aldrich

2-Aminobenzyl alcohol

98%

Synonym: 2-(Hydroxymethyl)aniline

  • CAS Number 5344-90-1

  • Linear Formula H2NC6H4CH2OH

  • Molecular Weight 123.15

  •  Beilstein/REAXYS Number 1072211

  •  EC Number 226-293-7

  •  MDL number MFCD00007749

  •  PubChem Substance ID 24847510

  •  NACRES NA.22

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Properties

Related Categories Amino Alcohols, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds More...
assay   98%
bp   162 °C/15 mmHg (lit.)
mp   81-83 °C (lit.)
storage temp.   room temp
SMILES string   Nc1ccccc1CO
InChI   1S/C7H9NO/c8-7-4-2-1-3-6(7)5-9/h1-4,9H,5,8H2
InChI key   VYFOAVADNIHPTR-UHFFFAOYSA-N

Description

General description

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.

Application

2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.

Packaging

10, 25 g in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
RTECS 
DN3155000
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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