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125482 Sigma-Aldrich

cis-Cyclooctene

contains 100-200 ppm Irganox 1076 FD as antioxidant, 95%

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Properties

Related Categories Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Organic Building Blocks More...
Quality Level   100
assay   95%
contains   100-200 ppm Irganox 1076 FD as antioxidant
refractive index   n20/D 1.469 (lit.)
bp   145-146 °C (lit.)
mp   −16 °C (lit.)
solubility   H2O: insoluble
density   0.846 g/mL at 25 °C (lit.)
storage temp.   room temp
SMILES string   C1CCCC=CCC1
InChI   1S/C8H14/c1-2-4-6-8-7-5-3-1/h1-2H,3-8H2/b2-1-
InChI key   URYYVOIYTNXXBN-UPHRSURJSA-N

Description

General description

cis-Cyclooctene undergoes addition reaction with carbon tetrachloride catalyzed by dichlorotris(triphenylphosphine) ruthenium(II) to yield 1-chloro-4-(trichloromethyl) cyclooctane (1,4-adduct). It undergoes epoxidation catalyzed by molybdenum oxide nanoparticles incorporated in a mesoporous silica shell coated on dense silica-coated magnetite nanoparticles.

Application

cis-Cyclooctene has been used to study the alkenes chemisorbed on silicon(100) by scanning tunneling microscopy.

Packaging

25 mL in glass bottle

Other Notes

Contains cyclooctane

Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Warning
Hazard statements 
RIDADR 
UN 3295C 3 / PGIII
WGK Germany 
WGK 2
Flash Point(F) 
77.0 °F - closed cup
Flash Point(C) 
25 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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