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144819 Sigma-Aldrich

1-(Trimethylsiloxy)cyclohexene

99%

Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether

  • CAS Number 6651-36-1

  • Linear Formula C6H9OSi(CH3)3

  • Molecular Weight 170.32

  •  Beilstein Registry Number 1859394

  •  EC Number 229-675-1

  •  MDL number MFCD00001541

  •  PubChem Substance ID 24848686

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Properties

Related Categories Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds More...
InChI Key   SBEMOANGDSSPJY-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.447(lit.)
bp   64-65 °C/15 mmHg(lit.)
density   0.875 g/mL at 25 °C(lit.)

Description

Packaging

5, 25 g in glass bottle

Application

1-(Trimethylsiloxy)cyclohexene was used in one-pot synthesis of Δ1,9- octalone. It is intermediate to many complex compounds including natural products.

General description

1-(Trimethylsiloxy)cyclohexene undergoes Michael addition reaction with methyl vinyl ketone in the presence of dibutyltin bis(triflate).

Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Warning
Hazard statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
105.8 °F
Flash Point(C) 
41 °C

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Protocols & Articles
Peer-Reviewed Papers
15

References

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