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145947 Sigma-Aldrich

Tetrachlorocyclopropene

98%

  • CAS Number 6262-42-6

  • Empirical Formula (Hill Notation) C3Cl4

  • Molecular Weight 177.84

  •  Beilstein/REAXYS Number 1099206

  •  EC Number 228-418-0

  •  MDL number MFCD00001267

  •  PubChem Substance ID 24848753

  •  NACRES NA.22

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Properties

Related Categories Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
InChI Key   BLZOHTXDDOAASQ-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.507 (lit.)
bp   125-130 °C (lit.)
density   1.45 g/mL at 25 °C (lit.)
storage temp.   2-8°C

Description

General description

Tetrachlorocyclopropene undergoes electrochemical reductive tert-butyldimethylsilylation to yield 1,2,3-tris(tert-butyldimethylsilyl)cyclopropene. It undergoes alkylation reaction with ferrocene in dichloromethane and AlCl3 to yield 2,3-diferrocenylcyclopropenone.

Application

Tetrachlorocyclopropene was used to prepare starting reagent for synthesis of 3,3-diethyl-and 3,3-dibenzyl-1,2-diferrocenylcyclopropenes.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
UN 2810 6.1 / PGII
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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