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14694 Sigma-Aldrich

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Synonym: Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex

  • CAS Number 35138-22-8

  • Empirical Formula (Hill Notation) C16H24BF4Rh

  • Molecular Weight 406.07

  •  MDL number MFCD00075045

  •  PubChem Substance ID 57647189

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts More...
Quality Level   100
composition   carbon content, 45.7-49.0%
mp   ~190 °C (dec.)
reaction suitability   reagent type: catalyst
SMILES string   [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2
InChI   1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1/b2*2-1-,8-7-;;
InChI key   NBGSCPNNKGVTKU-QMDOQEJBSA-N

Description

Packaging

100 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation; Hydrosilylation

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2921 4.1(8) / PGII
WGK Germany 
WGK 2
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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