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147389 Sigma-Aldrich

Triacetylmethane

97%

Synonym: 3-(1-Hydroxyethylidene)-2,4-pentanedione

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Properties

Related Categories Building Blocks, C7 to C8, Carbonyl Compounds, Chemical Synthesis, Ketones,
Quality Level   100
assay   97%
refractive index   n20/D 1.487 (lit.)
bp   203.5 °C (lit.)
density   1.066 g/mL at 25 °C (lit.)
SMILES string   C\C(O)=C(\C(C)=O)C(C)=O
InChI   1S/C7H10O3/c1-4(8)7(5(2)9)6(3)10/h8H,1-3H3
InChI key   IZKUHUPRYVVSHM-UHFFFAOYSA-N

Description

General description

Triacetylmethane on condensation with 2,6-diisopropylaniline in toluene in the presence of p-toluenesulfonic acid yields 3-[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione.

Application

Triacetylmethane was used in the synthesis of novel metal complexes bis(3-acetyl-2,4-pentanedionato-O2,O3)palladium(II) and bis(3-acetyl-2,4-pentanedionato-O2,O3)magnesium(II).

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
WGK Germany 
WGK 3

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Protocols & Articles
Peer-Reviewed Papers
15

References

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