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14826 Sigma-Aldrich

(R)-(+)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine

≥98.0% (CHN)

Synonym: (R)-(+)-N,N-Bis(2-diphenylphosphinoethyl)-α-methylbenzylamine

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Reduction
assay   ≥98.0% (CHN)
optical activity   [α]20/D +4.5±0.7°, c = 1% in acetone
SMILES string   C[C@@H](N(CCP(c1ccccc1)c2ccccc2)CCP(c3ccccc3)c4ccccc4)c5ccccc5
InChI   1S/C36H37NP2/c1-31(32-17-7-2-8-18-32)37(27-29-38(33-19-9-3-10-20-33)34-21-11-4-12-22-34)28-30-39(35-23-13-5-14-24-35)36-25-15-6-16-26-36/h2-26,31H,27-30H2,1H3/t31-/m1/s1
InChI key   ZVNAHLJBPYKGBV-WJOKGBTCSA-N

Description

Other Notes

Diphosphine ligand for iridium-cat. reduction of unsaturated ketones to allylalcohols

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3259PSN1 8 / PGIII
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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