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150533 Sigma-Aldrich

Thallium(III) trifluoroacetate

technical grade

Synonym: TTFA, Thallic trifluoroacetate, Trifluoroacetic acid thallium(III) salt, Tris(trifluoroacetato)thallium

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Thallium Catalysts More...
Quality Level   100
grade   technical grade
mp   213 °C (dec.) (lit.)
reaction suitability   reagent type: catalyst
storage temp.   2-8°C
SMILES string   FC(F)(F)C(=O)O[Tl](OC(=O)C(F)(F)F)OC(=O)C(F)(F)F
InChI   1S/3C2HF3O2.Tl/c3*3-2(4,5)1(6)7;/h3*(H,6,7);/q;;;+3/p-3
InChI key   PSHNNUKOUQCMSG-UHFFFAOYSA-K

Description

Packaging

5, 10, 50 g in glass bottle

Application

Oxidizing agent used in the synthesis of S-substituted cysteine peptides and proteins containing disulfide bonds.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1707 6.1 / PGII
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. ...
ChemFiles Volume 1 Article 3
Keywords: Organic synthesis, Oxidations, Reductions

Protocols

Fmoc SPPS Protocols for Cysteine Peptides

Peptides containing Cys can exist in either reduced (sulfhydryl) or oxidized inter/intra chain disulfide bonded forms. The synthesis of peptides containing Cys, therefore, presents special challenges...
Keywords: Alkylations, Asymmetric synthesis, Buffers, Centrifugation, Coupling reactions, Cyclizations, Eliminations, Evaporation, Filtration, High performance liquid chromatography, Hormones, Iodinations, Oxidations, Peptide synthesis, Purification, Racemizations, Rearrangements, Reductions, Solid phase peptide synthesis, Solvents, Thiolysis

Peer-Reviewed Papers
15

References

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