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151858 Sigma-Aldrich

Chloroform-d

"100%", 99.96 atom % D

Synonym: Deuterochloroform

  • CAS Number 865-49-6

  • Linear Formula CDCl3

  • Molecular Weight 120.38

  •  Beilstein/REAXYS Number 1697633

  •  EC Number 212-742-4

  •  MDL number MFCD00000827

  •  PubChem Substance ID 24849171

  •  NACRES NA.21

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Properties

Related Categories Alphabetical Listings, C, Chloroform, Chloroform-d, NMR Solvents,
Quality Level   100
isotopic purity   99.96 atom % D
assay   ≥99% (CP)
refractive index   n20/D 1.444 (lit.)
bp   60.9 °C (lit.)
mp   −64 °C (lit.)
density   1.500 g/mL at 25 °C (lit.)
mass shift   M+1
SMILES string   [2H]C(Cl)(Cl)Cl
InChI   1S/CHCl3/c2-1(3)4/h1H/i1D
InChI key   HEDRZPFGACZZDS-MICDWDOJSA-N

Description

General description

Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν1 and ν2 bands of CHCl3 and CDCl3.

Packaging

10×0.25, 10×0.5, 10×0.75, 10×1 mL in ampule

10, 50 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
RIDADR 
UN 1888 6.1 / PGIII
WGK Germany 
3

Dispensette™ S
Protocols & Articles

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Peer-Reviewed Papers
15

References

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