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151947 Sigma-Aldrich

Methanol-d4

≥99.8 atom % D

Synonym: Methyl-d3 alcohol d, Tetradeuteromethanol

  • CAS Number 811-98-3

  • Linear Formula CD3OD

  • Molecular Weight 36.07

  •  Beilstein/REAXYS Number 1733278

  •  EC Number 212-378-6

  •  MDL number MFCD00044637

  •  PubChem Substance ID 24849183

  •  NACRES NA.21

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Properties

Related Categories Alphabetical Listings, Common NMR Solvents, M, Methanol-d4, NMR Solvents,
Quality Level   200
isotopic purity   ≥99.8 atom % D
assay   ≥99% (CP)
form   liquid
expl. lim.   5.5-36.5 % (lit.)
application(s)   HPLC: suitable
impurities   ≤0.025% water
refractive index   n20/D 1.326 (lit.)
bp   65.4 °C (lit.)
mp   -99 °C (lit.)
density   0.888 g/mL at 25 °C (lit.)
SMILES string   [2H]OC([2H])([2H])[2H]
InChI   1S/CH4O/c1-2/h2H,1H3/i1D3,2D
InChI key   OKKJLVBELUTLKV-MZCSYVLQSA-N

Description

Application

Methanol-d4 may have been used as solvent in the nuclear magnetic resonance spectrum analysis for:
• characterizing phenolic compounds separated from olive oil using high performance liquid chromatography.
• vanillic acid and 4-hydroxy-3-methoxystyrene formed via biotransformation of Rhodotorula rubra.

Packaging

1 kg in glass bottle

100 g in Sure/Seal™

1, 5, 10 g in ampule

10 g in glass bottle

10 g in serum bottle

25, 50 g in glass bottle

50 g in serum bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN1230 - class 3 - PG 2 - Methanol
WGK Germany 
WGK 2
Flash Point(F) 
51.8 °F - closed cup
Flash Point(C) 
11 °C - closed cup
Protocols & Articles

Articles

NMR Deuterated Solvent Properties Reference Chart

Use the chart below to look up the coupling values — JHD and JCD(JCF) distance between multiplet peaks in hertz (Hz) — and chemical shift delta values — ðH(Mult)b and ðc(Mult)b in parts per million (...
Keywords: Melting, Nuclear magnetic resonance spectroscopy, Solvents

Pressure-Temperature Calculator for Solvents

*Calculations provide estimated results based on Antoine's Coefficients and their associated temperature range values. Antoine's Coefficients were obtained from the National Institute of Standards an...

Related Content

Pressure-Temperature Nomograph Interactive Tool

Use the interactive controls above to simplify calculations and improve the efficiency of your distillation or evaporation requirements.
Keywords: Evaporation, Vaporization

Properties of Solvents Chart

The solvent property charta lists the physical properties of solvents like Acetone, Benzene and Acetic Acid in alphabetical order for easier referencing. Use the solvent chart in the lab to find comm...
Keywords: Green chemistry, Melting, Solvents

Solvent Miscibility Table

Miscibility defines how substances combine (or mix) to form a homogenous solution without precipitates. Miscibility most often refers to liquids but can also apply to gas and solid phases.
Keywords: Calorimetry, Materials Science, PAGE, Pharmaceutical, Semiconductor, Separation, Solvents, Spectroscopy

Peer-Reviewed Papers
15

References

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