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155039 Sigma-Aldrich

Diphenyl(p-tolyl)phosphine

96%

Synonym: (4-Methylphenyl)diphenyl phosphine

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
assay   96%
mp   66-68 °C (lit.)
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   Cc1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI   1S/C19H17P/c1-16-12-14-19(15-13-16)20(17-8-4-2-5-9-17)18-10-6-3-7-11-18/h2-15H,1H3
InChI key   QJIMTLTYXBDJFC-UHFFFAOYSA-N

Description

Application

Reactant for:
• Three-component cyclization
• Probing coordination ability via a palladium pincer complex
• Chelation-assisted hydroacylation of olefins with primary alcohols

Reactant for synthesis of:
• Trinuclear ruthenium carbonyl triarylphosphine cluster complexes
• Leishmanicidal leads targeting mitochondria through inhibition of the respiratory complex
• InP nanofibers / metal phosphide nanostructures
• Peroxyl radical cations via pulse radiolysis one-electron oxidations

Packaging

10 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
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