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155349 Sigma-Aldrich

Thallium(I) cyclopentadienide

97%

Synonym: 5-Cyclopentadienyl)thallium, Cyclopentadienylthallium, NSC 114719, Thallous cyclopentadienide

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Properties

Related Categories Catalysis and Inorganic Chemistry, Catalysts for Polymerization, Chemical Synthesis, Materials Science, Olefin Polymerization,
Quality Level   100
assay   97%
mp   300 °C (lit.)
reaction suitability   reagent type: catalyst
reaction type: Olefin Metathesis
storage temp.   2-8°C
SMILES string   [Tl].[CH]1[CH][CH][CH][CH]1
InChI   1S/C5H5.Tl/c1-2-4-5-3-1;/h1-5H;
InChI key   RKLJDPOVAWGBSD-UHFFFAOYSA-N

Description

Application

Reagent in preparation of
• η5-Cyclopentadienylpalladium(II) complexes as catalysts for vinyl addition polymerization and copolymerization reactions
• Versatile carbon ligands via oxidative cyclization
• Isomeric dinuclear dicyclopentadienyl Ti chloride complexes containing bridging cyclopentadienylsiloxo ligands with Me Li and Lewis acids
• Bromide complexes of the triple-decker type
• Naphthylazo cyclopalladates via regiospecific naphthyl carbon-hydrogen bond activation

Reactant fro:
• Selective reduction of the U3+ metallocene amidinate

Packaging

10 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1707 6.1 / PGII
WGK Germany 
3
Protocols & Articles
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