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156485 Sigma-Aldrich

Mercury(II) trifluoroacetate

98%

Synonym: Bis(trifluoroacetoxy)mercury, Mercuric trifluoroacetate, Trifluoroacetic acid mercury(II) salt

  • CAS Number 13257-51-7

  • Linear Formula Hg(CF3COO)2

  • Molecular Weight 426.62

  •  Beilstein/REAXYS Number 3633860

  •  EC Number 236-250-4

  •  MDL number MFCD00013201

  •  PubChem Substance ID 24849613

  •  NACRES NA.23

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Mercury, Mercury Catalysts,
assay   98%
mp   171-173 °C (lit.)
SMILES string   FC(F)(F)C(=O)O[Hg]OC(=O)C(F)(F)F
InChI   1S/2C2HF3O2.Hg/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
InChI key   WMHOESUUCMEQMS-UHFFFAOYSA-L

Description

Packaging

10, 50 g in glass bottle

Application

Promotes selective cyclization of methylthio-substituted divinyl ketones to 5-fluorocyclopentenone derivatives.

Suitability

Reagent of choice for oxymercuration providing higher yields and greater selectivity. Fieser, M. Reagents for Organic Synthesis John Wiley and Sons: New York, 1992 Vol. 16, p 377 (Z233773). J. Org. Chem. 1990, 55, 5580.

Safety & Documentation

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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