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157910 Sigma-Aldrich

Methyl bromoacetate

97%

  • CAS Number 96-32-2

  • Linear Formula BrCH2COOCH3

  • Molecular Weight 152.97

  •  Beilstein/REAXYS Number 506256

  •  EC Number 202-499-2

  •  MDL number MFCD00000189

  •  PubChem Substance ID 24849708

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Properties

Related Categories Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   YDCHPLOFQATIDS-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.458 (lit.)
bp   51-52 °C/15 mmHg(lit.)
density   1.616 g/mL at 25 °C (lit.)

Description

General description

Methyl bromoacetate is an α-bromo ester. Reactions of the methyl bromoacetate with conjugate base of (methylmethoxycarbene)pentacarbonylchromium(0) yields alkylated carbene complexes.

Application

Methyl bromoacetate was used in the synthesis of novel coumarins. It was also employed in the synthesis of cis-cyclopropanes.

Packaging

25, 100 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2643 6.1 / PGII
WGK Germany 
3
RTECS 
AF6300000
Flash Point(F) 
147.2 °F
Flash Point(C) 
64 °C

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles
Peer-Reviewed Papers
15

References

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