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163015 Sigma-Aldrich

Thallium(III) nitrate trihydrate

Synonym: TTN, Thallium trinitrate

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Thallium Catalysts More...
Quality Level   100
mp   102-105 °C (lit.)
reaction suitability   reagent type: catalyst
SMILES string   O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI   1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3
InChI key   ZCPIKMRXMBJLCP-UHFFFAOYSA-N

Description

Application

Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.

Packaging

25, 100 g in glass bottle

Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
RIDADR 
UN 2727 5.1(6.1) / PGII
WGK Germany 
2
Protocols & Articles

Articles

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. ...
ChemFiles Volume 1 Article 3
Keywords: Organic synthesis, Oxidations, Reductions

Peer-Reviewed Papers
15

References

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