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171441 Aldrich

Trifluoroiodomethane

99%

Synonym: Iodotrifluoromethane, Perfluoromethyl iodide, Trifluoromethyl iodide

  • CAS Number 2314-97-8

  • Empirical Formula (Hill Notation) CF3I

  • Molecular Weight 195.91

  •  Beilstein Registry Number 1732740

  •  EC Number 219-014-5

  •  MDL number MFCD00001060

  •  PubChem Substance ID 24850061

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Properties

Related Categories Chemical Synthesis, Specialty Gases, Synthetic Reagents More...
InChI Key   VPAYJEUHKVESSD-UHFFFAOYSA-N
assay   99%
bp   −22.5 °C(lit.)
mp   <−78 °C (lit.)

Description

Application

Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,ß-unsaturated ketones.

Other Notes

In Europe, for 171441-100G-EU and 171441-100G packaging: 200 mL of aluminium cylinder equipped with stainless steel valve.

Packaging

25, 100 g in Sure-Pac™

Recommended products

• For 171441-25G/100G: Brass hose adapter Z146811 or brass body mini gas regulator Z513539 is recommended.
• In Europe, for 171441-100G-EU and 171441-100G: outlet fitting: DIN 477-1 no. 1, Z742162 or Z742164 are the recommended regulators.
• For 171441-100G and 171441-25G: outlet fitting no 99112 is the recommended outlet fitting.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1956 2.2
WGK Germany 
1

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Protocols & Articles

Articles

Reagents for Fluorination

The trifluoromethyl substituent has long been recognized for the positive influence it can have on the biological activity of molecules. Professor William Dolbier, Jr. (University of Florida) has dev...
Aldrich ChemFiles 2007, 7.1, 11.

Tetrakis(dimethylamino)ethylene (TDAE)

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the p...
Mark Redlich
Aldrich ChemFiles 2008, 8.3, 8.
Keywords: Organic synthesis

Peer-Reviewed Papers
15

References

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99112 Outlet valve No 70688, stainless steel, pkg of 1 ea

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