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176206 Sigma-Aldrich

Poly(methylhydrosiloxane)

Green Alternative

average Mn 1,700-3,200

Synonym: Methylhydrogensiloxane polymer, PMHS

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Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign reducing agent and has been enhanced for catalytic efficiency. Click here for more information.
Harnessing the reactivity of poly(methylhydrosiloxane) for the reduction and cyclization of biomass to high-value products

Application

Reducing agent.

Used in greener amine synthesis by reductive amination as an alternative to borohydrides.

Synthesis of substituted amines and isoindolinones: catalytic reductive amination using abundantly available AlCl3/PMHS

Amine Synthesis through Mild Catalytic Hydrosilylation of Imines using Polymethylhydroxysiloxane and [RuCl2(arene)]2 Catalysts

Packaging

50, 250 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
399.2 °F - closed cup
Flash Point(C) 
204 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Kit for PDMS Surface Modification

In collaboration with Clemson University and the Pennsylvania State University, we have developed a Surface Modification Kit, which allows for durable hydrophilization of various polydimethylsiloxane...
Keywords: Solvents

Micro and Nanometer Scale Photopatterning of Self-Assembled Monolayers

Graham J. Leggett* Department of Chemistry, University of Sheffield, Brook Hill, Sheffield S3 7HF, United Kingdom *Email: Graham.Leggett@shef.ac.uk
Keywords: Absorption, Adsorption, Degradations, Deposition, Microscopy, Optical microscopy, Oxidations, Polymerization reactions, Semiconductor, Spectroscopy

Organic Optoelectronics on Shape Memory Polymers

Center for Organic Photonics and Electronics (COPE), School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA *E-mail: bernard.kippelen@ece.gatech.e...
Canek Fuentes-Hernandez, Bernard Kippelen*
Material Matters, 2017, 12.3
Keywords: AGE, Adhesion, Atomic layer deposition, Biological processes, Catalysis, Ceramics, Deposition, Electronics, Environmental, Nanomaterials, Nanotubes, Oxidations, Photovoltaics, Polymerization reactions, Reductions, Semiconductor, Separation

Peer-Reviewed Papers
15

References

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