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177261 Sigma-Aldrich

DPPF

Green Alternative

97%

Synonym: 1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf

  • CAS Number 12150-46-8

  • Empirical Formula (Hill Notation) C34H28FeP2

  • Molecular Weight 554.38

  •  MDL number MFCD00001422

  •  PubChem Substance ID 24850625

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Properties

Related Categories 12 Principles Aligned Products, Buchwald Ligands and Complexes, Buchwald and Related Ligands, Catalysis, Catalysis and Inorganic Chemistry,
InChI Key   HPXNTHKXCYMIJL-UHFFFAOYSA-N
assay   97%
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   181-182 °C (dec.) (lit.)
reaction suitability   reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reagent type: ligand
reaction type: Carbonylations
  reagent type: ligand
reaction type: Ene Reaction
  reagent type: ligand
reaction type: Heck Reaction
  reagent type: ligand
reaction type: Negishi Coupling
  reagent type: ligand
reaction type: Sonogashira Coupling
  reagent type: ligand
reaction type: Stille Coupling
  reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
reaction type: Tsuji-Trost Reaction

Description

Packaging

1, 10, 25, 250 g in glass bottle

Application

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Development of Pd/C-Catalyzed Cyanation of Aryl Halides

An orthogonal set of catalyst systems has been developed for the Suzuki?Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for t...

Peer-Reviewed Papers
15

References

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