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178969 Aldrich

Tri-sec-butylborane solution

1.0 M in THF

Synonym: Tris(1-methylpropyl)borane

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   YUPAWYWJNZDARM-UHFFFAOYSA-N
concentration   1.0 M in THF
density   0.799 g/mL at 25 °C

Description

Packaging

100 mL in Sure/Seal™

Application

Catalyst for:
• Allylic alkylations for synthesis of unsaturated aldehydes and alcohols
• Cis-addition of carbon-hydrogen bonds of pyrroles and thiophenes to alkynes
• Borane-induced radical reduction of alkenyl and alkynyliodanes
• Initiating polymerization for synthesis of polymethylenes and ethylene-propylene
• Asymmetric synthesis of vinylglycidols
• Asymmetric addition of alcohols to vinyl epoxides

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Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
May form explosive peroxides.
RIDADR 
UN 2924 8(3) / PGII
WGK Germany 
1
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C
Protocols & Articles
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