• USA Home
  • 178969 - Tri-sec-butylborane solution

EMAIL THIS PAGE TO A FRIEND
178969 Sigma-Aldrich

Tri-sec-butylborane solution

1.0 M in THF

Synonym: Tris(1-methylpropyl)borane

  • CAS Number 1113-78-6

  • Linear Formula [C2H5CH(CH3)]3B

  • Molecular Weight 182.15

  •  MDL number MFCD00009325

  •  PubChem Substance ID 24850784

  •  NACRES NA.22

Purchase

Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
Quality Level   100
concentration   1.0 M in THF
density   0.799 g/mL at 25 °C
SMILES string   CCC(C)B(C(C)CC)C(C)CC
InChI   1S/C12H27B/c1-7-10(4)13(11(5)8-2)12(6)9-3/h10-12H,7-9H2,1-6H3
InChI key   YUPAWYWJNZDARM-UHFFFAOYSA-N

Description

Application

Catalyst for:
• Allylic alkylations for synthesis of unsaturated aldehydes and alcohols
• Cis-addition of carbon-hydrogen bonds of pyrroles and thiophenes to alkynes
• Borane-induced radical reduction of alkenyl and alkynyliodanes
• Initiating polymerization for synthesis of polymethylenes and ethylene-propylene
• Asymmetric synthesis of vinylglycidols
• Asymmetric addition of alcohols to vinyl epoxides

Packaging

100 mL in Sure/Seal™

Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
Target organs 
Respiratory system
Supplemental Hazard Statements 
EUH019
RIDADR 
UN 2924 8(3) / PGII
WGK Germany 
WGK 1
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C

Documents

Certificate of Analysis (COA)

Please Enter a Lot Number
Protocols & Articles
Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?