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179906 Sigma-Aldrich

Tributylborane solution

1.0 M in THF

Synonym: TBB, Tributylboron

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
Quality Level   100
concentration   1.0 M in THF
density   0.834 g/mL at 25 °C
SMILES string   CCCCB(CCCC)CCCC
InChI   1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
InChI key   CMHHITPYCHHOGT-UHFFFAOYSA-N

Description

Application

Reactant for:
• Addition reactions for synthesis of phenyltrialkylborate salts
• Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines
• Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists
• Multicomponent C-alkylation reactions with aromatic aldimines
• One-pot alkylation-boration and electrophilic substitution

Packaging

100 mL in Sure/Seal™

Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
Target organs 
Respiratory system
Supplemental Hazard Statements 
EUH019
RIDADR 
UN 1993BF 3 / PGII
WGK Germany 
WGK 1
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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