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184667 Sigma-Aldrich

(Chloromethyl)cyclopropane

97%

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Properties

Related Categories Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
InChI Key   ZVTQWXCKQTUVPY-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.435 (lit.)
bp   87-89 °C(lit.)
density   0.98 g/mL at 25 °C (lit.)

Description

General description

(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

Application

(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.

Packaging

10, 50 g in ampule

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993BF 3 / PGII
WGK Germany 
3
Flash Point(F) 
28.4 °F
Flash Point(C) 
-2 °C

Documents

Certificate of Analysis

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Protocols & Articles
Peer-Reviewed Papers
15

References

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accessory

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