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190780 Aldrich

Sodium trichloroacetate

97%

Synonym: NaTCA, TCA sodium salt, Trichloroacetic acid sodium salt

  • CAS Number 650-51-1

  • Linear Formula CCl3CO2Na

  • Molecular Weight 185.37

  •  Beilstein Registry Number 3773249

  •  EC Number 211-479-2

  •  MDL number MFCD00064198

  •  PubChem Substance ID 24851461

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Properties

Related Categories Chemical Synthesis, Inorganic Salts, Sodium, Synthetic Reagents
InChI Key   SAQSTQBVENFSKT-UHFFFAOYSA-M
assay   97%

Description

Packaging

100 g in poly bottle

5 g in glass bottle

Application

Sodium trichloroacetate with trichloroacetic acid (TCA) undergoes rapid decarboxylation in dimethylformamide (DMF) in the presence of aldehydes to form nucleophilic trichloromethyl anion, which then adds to the aldehydes to form trichloromethyl carbinols. It can also undergo thermal decarboxylation in aprotonic solvents in the presence of olefins to generate dichlorocarbene as an intermediate.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
2
RTECS 
AJ9100000

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Protocols & Articles
Peer-Reviewed Papers
15

References

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