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19997 Sigma-Aldrich

tert-Butyl hydroperoxide solution

packed in FEP bottles, ~5.5 M in decane (over molecular sieve 4Å)

Synonym: 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP

  • CAS Number 75-91-2

  • Linear Formula (CH3)3COOH

  • Molecular Weight 90.12

  •  Beilstein/REAXYS Number 1098280

  •  MDL number MFCD00002130

  •  PubChem Substance ID 57647815

  •  NACRES NA.23

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Properties

Related Categories Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides, Oxidizing Agents,
quality   packed in FEP bottles
concentration   ~5.5 M in decane (over molecular sieve 4Å)
refractive index   n20/D 1.403
density   0.83 g/mL at 20 °C
storage temp.   2-8°C
SMILES string   CC(C)(C)OO
InChI   1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key   CIHOLLKRGTVIJN-UHFFFAOYSA-N

Description

Application

Used in oxidative desulfurization of fuelsand as an oxidant for the epoxidation of styrene.

Packaging

25, 100 mL in PFA/FEP bottle

Other Notes

Safe and stable oxidant for the Sharpless epoxidation

Safety & Documentation

Safety Information

Signal word 
Danger
RIDADR 
UN 3105A8 8(5.2)
WGK Germany 
WGK 3
Flash Point(F) 
109.4 °F - closed cup
Flash Point(C) 
43 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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