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20423 Sigma-Aldrich

(tert-Butoxycarbonylmethyl)triphenylphosphonium chloride

≥98.0%

  • CAS Number 35000-37-4

  • Linear Formula (CH3)3COCOCH2P+(C6H5)3Cl

  • Molecular Weight 412.89

  •  Beilstein/REAXYS Number 4116684

  •  MDL number MFCD00043160

  •  PubChem Substance ID 57647835

  •  NACRES NA.22

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents More...
Quality Level   100
assay   ≥98.0%
reaction suitability   reaction type: C-C Bond Formation
storage temp.   room temp
SMILES string   [Cl-].CC(C)(C)OC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI   1S/C24H26O2P.ClH/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,19H2,1-3H3;1H/q+1;/p-1
InChI key   PWEGQXPODNSKMU-UHFFFAOYSA-M

Description

Application

Reactant for:
• Stereoselective preparation of (arylamino)quinazoline derivatives bearing tethered acrylamide moieties as inhibitors of epidermal growth factor receptor and histone deacetylase
• Thermal decomposition reactions

Packaging

25 g in poly bottle

Other Notes

Reagent for Wittig-reactions ; Synthesis of α-diazophosphonium salts

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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