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204242 Sigma-Aldrich

Bis(triphenylphosphine)rhodium(I) carbonyl chloride

99.9%

Synonym: Chlorocarbonylbis(triphenylphosphine)rhodium(I), RhCl(CO)(PPh3)2, Rhodiumbis(triphenylphosphine) carbonyl chloride

  • CAS Number 13938-94-8

  • Linear Formula [(C6H5)3P]2RhCl(CO)

  • Molecular Weight 690.94

  •  Beilstein/REAXYS Number 4618896

  •  EC Number 237-712-8

  •  MDL number MFCD00044273

  •  PubChem Substance ID 24852243

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts More...
assay   99.9%
mp   224-227 °C (dec.) (lit.)
reaction suitability   reagent type: catalyst
SMILES string   Cl[Rh].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI   1S/2C18H15P.CO.ClH.Rh/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h2*1-15H;;1H;/q;;;;+1/p-1
InChI key   SGULOPRLUCGLSH-UHFFFAOYSA-M

Description

Packaging

1 g in glass bottle

Application

Used for cyclometallation.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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