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205699 Aldrich

Palladium on carbon Green Alternative

extent of labeling: 10 wt. % loading, matrix activated carbon support

Synonym: Pd/C

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Properties

Related Categories Alternative Energy, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research,
InChI Key   KDLHZDBZIXYQEI-UHFFFAOYSA-N
greener alternative product characteristics   Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
extent of labeling   10 wt. % loading
matrix   activated carbon support

Description

Frequently Asked Questions

Frequently Asked Questions are available for this Product.

Application

The product can be used as catalyst for;
• hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics;
• hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides;
• dehydrogenate aromatics and deformylate aldehydes.

Catalyst for:
• Stille reaction
• Hydrogenation reactions
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions
• Deoxygenation
• Oxidation reactions
• Coupling reactions

Packaging

1, 10, 50, 250 g in glass bottle

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Price and Availability


LC-MS Grade Solvents and Reagents
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
nwg

Documents

Certificate of Analysis

Certificate of Origin

Frequently Asked Questions

Which document(s) contains shelf-life or expiration date information for a given product?
If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis. These documents are located on the product detail page under Useful Links & Tools. Click on the following link to search for a Certificate of Analysis. Please click the following link to see the details on our Product Dating Information.
How do I get lot-specific information or a Certificate of Analysis?
A Certificate of Analysis is available by lot number and can be obtained through our Advanced Search Option: http://www.sigmaaldrich.com/catalog/AdvancedSearchPage.do
How does product number 205699, Palladium on Carbon, differ from 330108, which is also 10 wt % palladium on activated carbon?
Product number 330108 is the wet support and appears as a moist black powder.  Product number 205699 is dry.
Is Product 205699, Palladium on carbon, reduced or unreduced?
It is reduced, but it can oxidize pretty readily.
What is the particle size of Product 205699, Palladium on carbon?
We expect the product to conform to the following: approximately 90% <60 µm and 10% <5 µm with an average particle size of 15 µm. 
What is the activity of Product 205699, Palladium on carbon?  How is the activity tested?  Is it a guaranteed value?
There is a fairly large variance in activity reported by the manufacturer on this material (from less than 50 ml/min to more than 100 ml/min).  Activity is not a specification but reported on the Certification of Analysis for further information.  Activity is measured by the hydrogen reduction of nitrobenzene. 
What is the surface area of Product 205699, Palladium on carbon?
The surface area of the carbon used as the support is 750-1000 m2 /g.  They do not test the surface area of the finished catalyst.
How do I find price and availability?
There are several ways to find pricing and availability for our products.  Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers. 
What is the Department of Transportation shipping information for this product?
Transportation information can be found in Section 14 of the product's (M)SDS. To access the shipping information for this material, use the link on the product detail page for the product, or search here. 
My question is not addressed here, how can I contact Technical Service for assistance?
Use the option to the right to "Ask a Question" by email of a Technical Service Scientist.
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Protocols & Articles

Articles

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ChemFiles Volume 1 Article 3

Peer-Reviewed Papers
15

References

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