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208671 Aldrich

Bis(triphenylphosphine)palladium(II) dichloride


Synonym: Dichlorobis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) dichloride, PdCl2(PPh3)2



Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium
assay   98%



Palladium-catalyzed coupling of iodo-α-β-unsaturated esters to afford tetrasubstituted olefins

Application Guide for Palladium Catalyzed Cross-Coupling Reactions


1, 5, 25, 100 g in glass bottle

Price and Availability

Screeing simplified
Safety & Documentation

Safety Information

NONH for all modes of transport
WGK Germany 

Frequently Asked Questions

Which document(s) contains shelf-life or expiration date information for a given product?
If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis. These documents are located on the product detail page under Useful Links & Tools. Click on the following link to search for a Certificate of Analysis. Please click the following link to see the details on our Product Dating Information.
How do I get lot-specific information or a Certificate of Analysis?
A Certificate of Analysis is available by lot number and can be obtained through our Advanced Search Option: http://www.sigmaaldrich.com/catalog/AdvancedSearchPage.do
What is a common use of Product 208671, Bis(triphenylphosphine)palladium(II) dichloride?  
This product is used as a transition method catalyst for Suzuki coupling reactions.  A variety of transition-metal catalysts are available from Aldrich. The majority of these catalysts are palladium- and nickel-based, typically utilizing phosphine-derived ligands.  Click on the below link to view our full list of transition-metal catalysts:  http://www.sigmaaldrich.com/Area_of_Interest/Chemistry/Chemical_Synthesis/Key_Resources/ChemFiles/Vol_2_No_1/Transition_Metal_Catalysts.html
What is Product 208671, Bis(triphenylphosphine)palladium(II) dichloride soluble in?
It is soluble in chloroform, toluene, and benzene.
Is Product 208671, Dichlorobis(triphenylphosphine)palladium(II), cis or trans?
We have not specifically tested the material in regards to what isomer it is, however, based on the synthesis of it, it is believed to be predominately trans.
How do I find price and availability?
There are several ways to find pricing and availability for our products.  Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers. 
What is the Department of Transportation shipping information for this product?
Transportation information can be found in Section 14 of the product's (M)SDS. To access the shipping information for this material, use the link on the product detail page for the product, or search here. 
My question is not addressed here, how can I contact Technical Service for assistance?
Use the option to the right to "Ask a Question" by email of a Technical Service Scientist.
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Protocols & Articles


Transition-Metal Catalysts

A variety of transition-metal catalysts for the Suzuki coupling reaction are available from Aldrich. The majority of these catalysts are palladium- and nickelbased, typically utilizing phosphine-deri...
ChemFiles Volume 1 Article 1
Keywords: Coupling reactions, Ligands, Suzuki coupling

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