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213012 Sigma-Aldrich

Benzeneseleninic acid anhydride

70%

  • CAS Number 17697-12-0

  • Linear Formula C6H5SeOOSeOC6H5

  • Molecular Weight 360.13

  •  Beilstein/REAXYS Number 2332406

  •  MDL number MFCD00001991

  •  PubChem Substance ID 24852763

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Selenium Compounds
Quality Level   200
assay   70%
impurities   <30% benzeneseleninic acid
mp   165-170 °C (lit.)
SMILES string   O=[Se](O[Se](=O)c1ccccc1)c2ccccc2
InChI   1S/C12H10O3Se2/c13-16(11-7-3-1-4-8-11)15-17(14)12-9-5-2-6-10-12/h1-10H
InChI key   FHPZOWOEILXXBD-UHFFFAOYSA-N

Description

General description

Oxidation of phenols by benzeneseleninic acid anhydride yields ortho-quinones. Benzeneseleninic anhydride acts as a mild oxidant for the conversion of benzylic hydrocarbons into aldehydes or ketones.

Application

Benzeneseleninic acid anhydride was used to oxidize hydrazines to afford azo-compounds.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 3283 6.1 / PGIII
WGK Germany 
3

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Protocols & Articles
Peer-Reviewed Papers
15

References

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