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223670 Sigma-Aldrich

Bis(cyclopentadienyl)zirconium(IV) chloride hydride

95%

Synonym: Di(cyclopentadienyl)zirconium(IV) chloride hydride, Schwartz’ reagent, Zirconocene chloride hydride

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Metal Hydrides, Reduction, Synthetic Reagents,
Quality Level   100
assay   95%
reaction suitability   reagent type: catalyst
SMILES string   [H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI   1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1
InChI key   PSYHEBZUPSHSKK-UHFFFAOYSA-M

Description

Application

Bis(cyclopentadienyl)zirconium(IV) chloride hydride can be used:
• To convert amides to aldehydes.
• As a reagent for the functionalization of olefins and alkynes.
• As a reducing agent in the preparation of (E)-vinyl organochalcogenides.
• To prepare a dioxaborolane derivative, which is a key intermediate for the synthesis of bridged-nicotine analogs.

Packaging

1, 5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 3131 8(4.3) / PGII
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Reagents for C–C Bond Formation

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used al...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations

Peer-Reviewed Papers
15

References

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