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224839 Sigma-Aldrich

Bismuth(III) chloride

reagent grade, ≥98%

Synonym: Bismuth trichloride, Trichlorobismuth

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Properties

Related Categories Bismuth Catalysts, Bismuth Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals,
grade   reagent grade
InChI Key   JHXKRIRFYBPWGE-UHFFFAOYSA-K
assay   ≥98%
bp   447 °C(lit.)
mp   230-232 °C (lit.)

Description

General description

Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine.

Application

Bismuth(III) chloride may be used as a catalyst in the following processes:
• Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols.
• Preparation of thiiranes from oxiranes using ammonium thiocyanate.
• Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates.
• Allylation of secondary benzyl alcohols with allyltrimethylsilane.
• [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles.

Packaging

25, 100, 500 g in poly bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
2
RTECS 
EB2690000

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles
Peer-Reviewed Papers
15

References

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