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  • 227226 - 1-(Trimethylsiloxy)-1,3-butadiene

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227226 Sigma-Aldrich

1-(Trimethylsiloxy)-1,3-butadiene

98%

  • CAS Number 6651-43-0

  • Linear Formula (CH3)3SiOCH=CHCH=CH2

  • Molecular Weight 142.27

  •  Beilstein Registry Number 1902024

  •  MDL number MFCD00009647

  •  PubChem Substance ID 24853620

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Properties

Related Categories Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds More...
InChI Key   UQGOYQLRRBTVFM-VOTSOKGWSA-N
assay   98%
refractive index   n20/D 1.448(lit.)
bp   131 °C(lit.)
density   0.811 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

10, 50 g in glass bottle

Application

1-(Trimethylsiloxy)-1,3-butadiene is commonly employed as diene in the Diels-Alder reaction.

General description

Mechanism of Diels-Alder reaction between 1-(trimethylsiloxy)-1,3-butadiene and 4,6-dinitrobenzofuroxan has been studied using state-of-the-art computational methods.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
77 °F
Flash Point(C) 
25 °C

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Protocols & Articles

Articles

Acids and Bases

Acids and bases have been used by chemists for centuries, and are among the most fundamental reagents employed in synthetic organic chemistry. This product line ranges from Brønsted and Lewis acids, ...
Chemfiles Volume 1 Article 3

Reagents for C–C Bond Formation

Aldrich carries a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations

Peer-Reviewed Papers
15

References

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