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  • 227803 - (−)-Diisopropyl D-tartrate

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227803 Sigma-Aldrich

(−)-Diisopropyl D-tartrate

98%

Synonym: D-(−)-Tartaric acid diisopropyl ester

  • CAS Number 62961-64-2

  • Linear Formula [-CH(OH)CO2CH(CH3)2]2

  • Molecular Weight 234.25

  •  Beilstein/REAXYS Number 5265431

  •  EC Number 263-771-4

  •  MDL number MFCD00008876

  •  PubChem Substance ID 24853655

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Chiral Resolution Reagents,
assay   98%
optical activity   [α]23/D −17°, neat
optical purity   ee: ≥99% (GLC)
refractive index   n20/D 1.439 (lit.)
density   1.119 g/mL at 20 °C (lit.)
storage temp.   room temp
SMILES string   CC(C)OC(=O)[C@@H](O)[C@H](O)C(=O)OC(C)C
InChI   1S/C10H18O6/c1-5(2)15-9(13)7(11)8(12)10(14)16-6(3)4/h5-8,11-12H,1-4H3/t7-,8-/m0/s1
InChI key   XEBCWEDRGPSHQH-YUMQZZPRSA-N

Description

Application

Both D- and L-forms are reagents for kinetic resolution of racemic allylic alcohols and α-furfuryl amides by enantioselective epoxidation.

Packaging

10, 50 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
230.0 °F - closed cup
Flash Point(C) 
110 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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