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227951 Sigma-Aldrich

Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Green Alternative

98%

Synonym: 1,5-Cyclooctadienerhodium(I) chloride dimer, Bis(1,5-cyclooctadiene)dirhodium(I) dichloride, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer, [Rh(COD)Cl]2

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Properties

Related Categories 12 Principles Aligned Products, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research,
Quality Level   100
assay   98%
reaction suitability   core: rhodium
  reagent type: catalyst
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   243 °C (dec.) (lit.)
SMILES string   Cl[Rh].Cl[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
InChI   1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
InChI key   QSUDXYGZLAJAQU-MIXQCLKLSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Efficient and Selective Catalysts for Asymmetric Synthesis

Catalyst for coupling 1,3-dienes with activated hydrocarbons and for preparing chiral complexes.

Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Packaging

5, 50 g in glass bottle

500 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Direct Arylation of Heterocycles

Lewis and co-workers have recently disclosed a highly functional-group compatible Rh-catalyzed C-H bond activation for the rapid synthesis of functionalized heterocycles. The method relies on the use...
Josephine Nakhla
ChemFiles 2009, 9.2, 8.
Keywords: Arylations, Catalysis, Dehydrogenation, Hydrohalogenations, Ligands, Reductions

Related Content

Hayashi Catalysts in Chemical Synthesis

The Hayashi group at Kyoto University has spearheaded the development of rhodium-based catalysts applied in the asymmetric, conjugate addition of arylboronic acids to C=C bonds.1 They utilized Rh-BIN...
Keywords: Addition reactions, Asymmetric synthesis, Building blocks, Catalysis, Eliminations

Peer-Reviewed Papers
15

References

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