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229024 Sigma-Aldrich

R-Alpine-Hydride®

0.5 M in THF

Synonym: Lithium B-isopinocampheyl-9-borabicyclo[3.3.1]nonyl hydride solution

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Reduction
optical activity   [α]20/D −8.5°
concentration   0.5 M in THF
density   0.919 g/mL at 25 °C (lit.)
SMILES string   [Li+].C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)[BH-]3[C@@H]4CCC[C@H]3CCC4
InChI   1S/C18H32B.Li/c1-12-16-10-13(18(16,2)3)11-17(12)19-14-6-4-7-15(19)9-5-8-14;/h12-17,19H,4-11H2,1-3H3;/q-1;+1/t12-,13+,14-,15+,16-,17-,19?;/m1./s1
InChI key   JBOSJEWMOTWSER-ZEBZFEJDSA-N

Description

Packaging

100 mL in Sure/Seal™

Other Notes

Made from (+)-α-pinene

Legal Information

Alpine-Hydride is a registered trademark of Sigma-Aldrich Co. LLC

Safety & Documentation

Safety Information

Signal word 
Danger
Supplemental Hazard Statements 
May form explosive peroxides.
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
3
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C
Protocols & Articles
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