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229628 Aldrich

Copper(I) chloride

≥99.995% trace metals basis

Synonym: Copper monochloride, Cuprous chloride

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Properties

Related Categories ATRP, ATRP Metal Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper,
vapor pressure   1.3 mmHg ( 546 °C)
InChI Key   OXBLHERUFWYNTN-UHFFFAOYSA-M
assay   ≥99.995% trace metals basis
form   powder
bp   1490 °C(lit.)
mp   430 °C(lit.)
solubility   slightly soluble 0.47 g/L at 20 °C
Featured Industry   Battery Manufacturing

Description

Packaging

10, 100 g in poly bottle

Application

CuCl may be used as an initiator for hydrostannation of α,α-unsaturated ketones and other similar radical reactions.
Shows unique character as an initiator of radical reactions such as the hydrostannation of α,β-unsaturated ketones.

Shows unique character as an initiator of radical reactions such as the hydrostannation of α,β-unsaturated ketones.

General description

The structure of copper(I) chloride is similar to zinc-blende crystal at room temperature; the structure is wurtzite at 407 °C and at higher temperatures it forms copper(I) chloride vapor as per mass spectroscopy.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Personal Protective Equipment 
RIDADR 
UN 2802 8 / PGIII
WGK Germany 
3
RTECS 
GL6990000

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteri...
Keywords: Biomaterials, Living polymerization, Nanotechnology, Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations, transformation

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

In 2006, Matyjaszewski and co-workers first described controlled radical polymerization by Activators ReGenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP),1-3 a developm...
Keywords: Antimicrobials, Ligands, Nanotubes, Oxidations, Polymerization reactions, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization, Solvents

Concepts and Tools for RAFT Polymerization

RAFT or Reversible Addition/Fragmentation Chain Transfer is a form of living radical polymerization. RAFT polymerization was discovered at CSIRO in 1998.1 It soon became the focus of intensive resear...
Keywords: Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

Emergence of living radical polymerization mediated by transition metal catalysts in 1995 was a seminal piece of work in the field of synthetic polymer chemistry.1-3 Since this date, many transition ...
Keywords: Catalysis, Condensations, Evaporation, Filtration, Ligands, Oxidations, Polymer science, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Solvents

Lanthanide Ions as Photon Managers for Solar Cells

Global energy consumption is on the rise and is projected to double by 2050, compared with worldwide energy consumption rates in 2001.1 Sustainable energy production based on the direct conversion of...
Keywords: Absorption, Capillary electrophoresis, Infrared spectroscopy, Nanomaterials, Photovoltaics, Reductions, Semiconductor, Solar cells

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. ...
ChemFiles Volume 1 Article 3
Keywords: Organic synthesis, Oxidations, Reductions, Tools

Thermoelectric Performance of Perovskite-type Oxide Materials - Material Matters, 2011, Volume 6, Number 4, 92–99

Lassi Karvonen, Petr Tomeš, Anke Weidenkaff* Laboratory for Solid State Chemistry and Catalysis Department of Mobility, Energy and Environment EMPA-Swiss Federal Laboratories for Materials Science an...
Lassi Karvonen, Petr Tomeš, Anke Weidenkaff
Material Matters, 2011, Volume 6, Number 4, 92–99
Keywords: Applications, Catalysis, Ceramics, Combustion, Degradations, Materials Science, Oxidations, Search, Semiconductor, Substitutions, Support, Type

Thermoelectric Performance of Perovskite-type Oxide Materials - Materials Science

Lassi Karvonen, Petr Tomeš, Anke Weidenkaff* Laboratory for Solid State Chemistry and Catalysis Department of Mobility, Energy and Environment EMPA-Swiss Federal Laboratories for Materials Science an...
Keywords: Catalysis, Combustion, Degradations, Materials Science, Oxidations, Semiconductor, Substitutions

Tools for Performing ATRP (Atom Transfer Radical Polymerization)

Controlled radical polymerization (CRP) techniques have been reviewed in a number of articles1,2 and books,3 and include nitroxide-mediated polymerization (NMP),4-7 reversible addition fragmentation ...
Keywords: Ligands, Materials Science, Polymerization reactions, Purification, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization

Typical Procedures for Polymerizing via ATRP

The following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.
Keywords: Gas chromatography, Ligands, Nuclear magnetic resonance spectroscopy, Polymerization reactions, Size-exclusion chromatography, Solvents

Typical Procedures for Polymerizing via RAFT

RAFT (Reversible Addition/Fragmentation Chain Transfer) is a form of living radical polymerization involving conventional free radical polymerization of a substituted monomer in the presence of a sui...
Keywords: Nuclear magnetic resonance spectroscopy, Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations

Peer-Reviewed Papers
15

References

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