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230502 Sigma-Aldrich

Copper(I) bromide dimethyl sulfide complex

99%

Synonym: Copper(I) bromide methyl sulfide complex, Cuprous bromide dimethyl sulfide complex, Cuprous bromide methyl sulfide complex

  • CAS Number 54678-23-8

  • Linear Formula CuBr · CH3SCH3

  • Molecular Weight 205.58

  •  Beilstein/REAXYS Number 4386581

  •  EC Number 259-292-5

  •  MDL number MFCD00043295

  •  PubChem Substance ID 24853810

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper Catalysts, Copper Salts, Essential Chemicals,
Quality Level   200
assay   99%
reaction suitability   core: copper
  reagent type: catalyst
mp   132 °C (dec.) (lit.)
SMILES string   [Cu]Br.CSC
InChI   1S/C2H6S.BrH.Cu/c1-3-2;;/h1-2H3;1H;/q;;+1/p-1
InChI key   PMHQVHHXPFUNSP-UHFFFAOYSA-M

Description

Packaging

10, 50 g in glass bottle

Application

Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to [60]fullerene and 3 groups to [70]fullerene.

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
UN 3335
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Reagents for C–C Bond Formation

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used al...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations

Peer-Reviewed Papers
15

References

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