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232904 Sigma-Aldrich

Methyl 3-amino-2-thiophenecarboxylate

99%

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Properties

Related Categories Building Blocks, C4 to C6, Chemical Synthesis, Heterocyclic Building Blocks, Thiophenes More...
InChI Key   TWEQNZZOOFKOER-UHFFFAOYSA-N
assay   99%
bp   100-102 °C/0.1 mmHg(lit.)
mp   62-64 °C (lit.)

Description

Packaging

10, 50 g in glass bottle

Application

Methyl 3-amino-2-thiophenecarboxylate was used in:
• the synthesis of 4-nitro and 4-aminothienyl ureas
• total synthesis of quinazolinocarboline alkaloids
• preparation of thienopyrimidinone analogs

General description

Methyl 3-amino-2-thiophenecarboxylate reacts with hydrazonoyl chlorides in the presence of triethylamine to yield corresponding N-arylamidrazones.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
RTECS 
XM8347500

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Protocols & Articles
Peer-Reviewed Papers
15

References

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