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237310 Sigma-Aldrich

Methyl 2-bromobutyrate

97%

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Properties

Related Categories Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   UFQQDNMQADCHGH-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.452 (lit.)
bp   137-138 °C/50 mmHg(lit.)
density   1.573 g/mL at 25 °C (lit.)

Description

Application

Methyl 2-bromobutyrate has been employed as reagent in the synthesis of:
• racemic indene ester via Reformatsky reaction with 5-methoxy-1-indanone
• (E)-2-methoxymethylene-butyric acid methyl ester via Reformatsky reaction with α,α-dichloromethyl methyl ether in the presence of zinc dust
• (E)-2-methoxymethylene-butyryl chloride

Packaging

100 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3265 8 / PGIII
WGK Germany 
3
Flash Point(F) 
154.4 °F
Flash Point(C) 
68 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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