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242403 Sigma-Aldrich

(Bromomethyl)cyclopropane

97%

Synonym: Cyclopropylmethyl bromide

  • CAS Number 7051-34-5

  • Linear Formula C3H5CH2Br

  • Molecular Weight 135.00

  •  Beilstein/REAXYS Number 605296

  •  EC Number 230-331-8

  •  MDL number MFCD00001306

  •  PubChem Substance ID 24854557

  •  NACRES NA.22

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Properties

Related Categories Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
Quality Level   100
assay   97%
refractive index   n20/D 1.457 (lit.)
bp   105-107 °C (lit.)
density   1.392 g/mL at 25 °C (lit.)
SMILES string   BrCC1CC1
InChI   1S/C4H7Br/c5-3-4-1-2-4/h4H,1-3H2
InChI key   AEILLAXRDHDKDY-UHFFFAOYSA-N

Description

General description

The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

Application

(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Packaging

1, 5 g in ampule

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
105.8 °F
Flash Point(C) 
41 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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