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243965 Sigma-Aldrich

Phenylselenyl bromide

98%

Synonym: Benzeneselenenyl bromide, Benzeneselenyl bromide

  • CAS Number 34837-55-3

  • Linear Formula C6H5SeBr

  • Molecular Weight 235.97

  •  Beilstein/REAXYS Number 2039772

  •  EC Number 252-238-1

  •  MDL number MFCD00000047

  •  PubChem Substance ID 24854643

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Selenium Compounds
Quality Level   100
assay   98%
bp   107-108 °C/15 mmHg (lit.)
mp   58-62 °C (lit.)
SMILES string   Br[Se]c1ccccc1
InChI   1S/C6H5BrSe/c7-8-6-4-2-1-3-5-6/h1-5H
InChI key   LCEFEIBEOBPPSJ-UHFFFAOYSA-N

Description

Application

Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione. It was also used in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN2928 - class 6.1 - PG 2 - EHS- -acidic - Toxic solids, corrosive, organic, n.o.s., HI: all
WGK Germany 
3

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Protocols & Articles
Peer-Reviewed Papers
15

References

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